HomePetro Productn-Butene

n-Butene

What is n-Butene

n-Butene (also written as n-butylene) refers to a group of four-carbon straight-chain olefins (alkenes) with the molecular formula C4H8, existing as three structural isomers: 1-butene (double bond at C1), cis-2-butene, and trans-2-butene (double bond at C2). All three are colorless, flammable gases at ambient conditions with boiling points near or slightly above 0 °C. n-Butene is primarily obtained as a co-product of steam cracking of naphtha or ethane for ethylene production, and from fluid catalytic cracking (FCC) in oil refineries. It is a key petrochemical intermediate used in the production of polybutylene, butadiene (via oxidative dehydrogenation), methyl ethyl ketone (MEK), sec-butanol, isobutylene (via skeletal isomerization), and as a comonomer in linear low-density polyethylene (LLDPE). It is also used as a fuel blending component and alkylation feedstock in refineries.

Analysts Sentiment

Bullish

33.7%

Neutral

33.8%

Bearish

32.5%

1-Week Outlook, Updated: June 8, 2026 | Next Update: June 15, 2026

What's driving sentiment this week:

Past Week (2026-06-01 to 2026-06-07) — Sentiment: Neutral

No new supply disruptions or expansions drove n-Butene availability last week, leaving supply steady.

Demand factors remained flat without significant changes in downstream ethylene or polymer plant operations through early June.

Geopolitical and macroeconomic conditions showed no material shocks impacting trade flows or feedstock costs during this period.

This Week (2026-06-08 to 2026-06-14) — Outlook: Neutral

Market prices are expected to rangebound given the absence of immediate catalysts in supply or demand.

The main focus will be on North American cracker maintenance schedules (expected), which could modestly influence spot tightness late this week.

A sudden surge in crude oil prices or an unforeseen supply disruption in petrochemical hubs would shift the tone sharply higher.

Key Market Impact

Current fundamentals see balanced supply-demand forces maintaining margins and utilization near prior levels.

Traders and buyers are likely to hold off large commitments and await clearer directional signals from upstream cracker utilization data.

How About the Price?

Monthly n-Butene Price History (USD/ton)
Month Price (USD/ton) Change Change Rate
2026-06-08 178.3 57.8 47.97%
2020-01 120.5 0 0%

Price Trajectory 2020–2026 (Brief Recap)

Phase 1 — Stable baseline (2020): Prices held steady at $120.5 per ton with no recorded influencing factors in the events log.

Phase 2 — Rising trend (2026): Prices increased sharply to $178.3 per ton by June 8, 2026, with no specific events documented in the influence log to explain this rise.

Supply-side factors

  • No recorded supply-side factors impacting price from 2020 through mid-2026 as per the events log.

Demand-side factors

  • No recorded demand-side factors impacting price from 2020 through mid-2026 as per the events log.

Substitutes & Alternatives

SubstituteReplacement Scenario / How It Substitutes
1-HexeneUsed as a comonomer in LLDPE production in place of 1-butene. Produces LLDPE with superior film toughness and puncture resistance. Requires no process reformulation for Ziegler-Natta or metallocene catalyst systems; the switch is largely a feedstock change at the polymerization reactor. Preferred when higher comonomer incorporation efficiency is desired.
1-OcteneHigher alpha-olefin comonomer for LLDPE and VLDPE, substituting 1-butene where enhanced mechanical properties (tear strength, elongation) are required. Drop-in at the reactor level but commands a price premium. Produced via ethylene oligomerization (e.g., SHOP process).
Isobutylene (Isobutene)Substitutes n-butene in alkylation units (refinery gasoline production) and as a C4 olefin feedstock for fuel blending. In MTBE/ETBE synthesis, isobutylene is the preferred feedstock over n-butene. For butyl rubber production, isobutylene is the direct monomer and cannot be replaced by n-butene, but in mixed C4 alkylation feeds, n-butene and isobutylene are interchangeable to a degree.
PropylenePartial substitute in polymer applications: polypropylene can replace polybutylene in certain packaging and pipe applications. In refinery alkylation, propylene can substitute n-butene as an alkylation feedstock, though octane yield and product distribution differ. Requires process and formulation adjustments.
n-Butane (with dehydrogenation)On-purpose feedstock substitute: n-butane can be catalytically dehydrogenated to produce n-butene (and further to butadiene), making it an upstream substitute when n-butene supply is tight. Not a direct drop-in but an alternative production route that effectively replaces steam-cracker-derived n-butene.
Ethylene (via metathesis)In the Shell Higher Olefins Process (SHOP) and similar metathesis routes, ethylene reacts with 2-butene to produce 1-butene, or internal olefins are redistributed. Ethylene thus acts as a functional substitute feedstock for generating 1-butene comonomer, bypassing the need to source it directly from C4 cracker streams.
Butadiene (hydrogenation)Selective hydrogenation of butadiene present in crude C4 streams can convert it to n-butene, effectively using butadiene as a precursor/substitute feedstock to increase n-butene yield within an existing C4 processing train. Used when butadiene market prices are low relative to butene values.

Regulatory Status

RegionRegulation / Policy NameIssuing AuthorityYear (enacted or latest revision)Key Requirement / ThresholdSource
USNational Volatile Organic Compound Emission Standards for Aerosol CoatingsUS EPA2025Reactivity-based VOC limits and reactivity factors for consumer products; no specific threshold for n-ButeneUS EPA (https://www.epa.gov/stationary-sources-air-pollution/aerosol-coatings-national-volatile-organic-compound-emission)
EURegulation (EC) No 1907/2006 (REACH)ECHA2006REACH registration required for n-Butene (EC No. 203-449-2, REACH registration number 01-2119456615-34)ECHA (https://chem.echa.europa.eu/)
EURegulation (EC) No 1272/2008 (CLP)ECHA2008Hazard classification (flammable gas) and labellingECHA (https://chem.echa.europa.eu/)
ChinaRegulations on the Control over Safety of Hazardous ChemicalsMinistry of Ecology and Environment2011Management of hazardous chemicals; registration required for n-ButeneMinistry of Ecology and Environment (https://www.mee.gov.cn/)
ChinaMeasures on Environmental Management Registration of New Chemical SubstancesMinistry of Ecology and Environment2020Environmental management registration for new chemical substancesMinistry of Ecology and Environment (https://www.mee.gov.cn/)
USOSHA Hazard Communication StandardOSHA2012 (current)GHS classification (flammable gas); exposure limits for butenes isomersOSHA (https://www.osha.gov/)
USNIOSH Pocket Guide to Chemical HazardsNIOSHongoingExposure limit TWA 800 ppm (1900 mg/m³); flammable gas classificationNIOSH (https://www.cdc.gov/niosh/)

Key Influence Events

No influence events available.

n-Butene (also written as n-butylene) refers to a group of four-carbon straight-chain olefins (alkenes) with the molecular formula C4H8, existing as three structural isomers: 1-butene (double bond at C1), cis-2-butene, and trans-2-butene (double bond at C2). All three are colorless, flammable gases at ambient conditions with boiling points near or slightly above 0 °C. n-Butene is primarily obtained as a co-product of steam cracking of naphtha or ethane for ethylene production, and from fluid catalytic cracking (FCC) in oil refineries. It is a key petrochemical intermediate used in the production of polybutylene, butadiene (via oxidative dehydrogenation), methyl ethyl ketone (MEK), sec-butanol, isobutylene (via skeletal isomerization), and as a comonomer in linear low-density polyethylene (LLDPE). It is also used as a fuel blending component and alkylation feedstock in refineries.

Top Countries Production Capacity

Average n-Butene Capacity by Country/Region in 2025 (tons/year)
Rank Country / Region Average Daily Production (tons/year)
Global Total1750000
1 China 620000
2 United States 300000
3 Saudi Arabia 100000
4 Japan 70000
5 South Korea 60000
6 India 50000
7 Germany 40000
8 France 30000
9 Italy 25000
10 Canada 20000
11 United Kingdom 18000
12 Brazil 15000
13 Turkey 12000
14 Indonesia 10000
15 South Africa 8000

Production Process of n-Butene

n-Butene (also written as n-butylene) refers to a group of four-carbon straight-chain olefins (alkenes) with the molecular formula C4H8, existing as three structural isomers: 1-butene (double bond at C1), cis-2-butene, and trans-2-butene (double bond at C2). All three are colorless, flammable gases at ambient conditions with boiling points near or slightly above 0 °C. n-Butene is primarily obtained as a co-product of steam cracking of naphtha or ethane for ethylene production, and from fluid catalytic cracking (FCC) in oil refineries. It is a key petrochemical intermediate used in the production of polybutylene, butadiene (via oxidative dehydrogenation), methyl ethyl ketone (MEK), sec-butanol, isobutylene (via skeletal isomerization), and as a comonomer in linear low-density polyethylene (LLDPE). It is also used as a fuel blending component and alkylation feedstock in refineries.

Specs & Grades

PropertyTypical Value / RangeUnitGrade / Note
1-Butene purity (polymer grade)≥ 99.5wt%Polymer Grade 1-Butene
1-Butene purity (chemical grade)≥ 98.0wt%Chemical Grade 1-Butene
2-Butene content (in 1-butene grade)≤ 0.3wt%Polymer Grade
Isobutylene content (in 1-butene grade)≤ 0.1wt%Polymer Grade
Butadiene content≤ 10ppm wtPolymer Grade
Total sulfur≤ 1ppm wtPolymer Grade
Water content≤ 5ppm wtPolymer Grade
Acetylene content≤ 5ppm wtPolymer Grade
CO + CO2 content≤ 5ppm wtPolymer Grade
Oxygen content≤ 2ppm wtPolymer Grade
Mixed n-Butene (refinery grade, C4 raffinate)1-butene + 2-butene ≥ 50wt%Refinery / Alkylation Grade
Boiling point (1-butene)-6.3°CPure component
Boiling point (cis-2-butene)3.7°CPure component
Boiling point (trans-2-butene)0.9°CPure component
Vapor pressure at 20 °C (1-butene)~2.0bar absPure component
Density (liquid, 1-butene at 20 °C)~595kg/m³Pure component

Who are the Top Players?

CompanyHeadquartersKey Facilities
Evonik Industries AGEssen, North Rhine-Westphalia, GermanyBaytown TX
TPC GroupHouston, Texas, USAHouston TX
Chevron Phillips Chemical Company LLCHouston, Texas, USACedar Bayou TX, Baytown TX
SinopecBeijing, ChinaZhenhai, Maoming, Qilu, Lanzhou, Dushanzi
Reliance Industries LimitedMumbai, Maharashtra, IndiaJamnagar
PTT Global Chemical Public Company LimitedBangkok, ThailandMap Ta Phut
PetrokemyaYanbu, Saudi ArabiaYanbu
INEOS Group Holdings S.A.London, England, United KingdomGrangemouth, Cologne
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