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Dioctyl Phthalate

What is Dioctyl Phthalate

Dioctyl Phthalate (DOP), also known as Di(2-ethylhexyl) phthalate (DEHP), is a colorless, oily liquid with the chemical formula C24H38O4 and CAS number 117-81-7. It is the most widely used general-purpose plasticizer in the world, primarily employed to impart flexibility, durability, and workability to polyvinyl chloride (PVC) and other polymers. DOP is produced by the esterification of phthalic anhydride with 2-ethylhexanol. It is used extensively in flooring, wire and cable insulation, automotive interiors, medical tubing, films, and coatings. Due to regulatory concerns about its endocrine-disrupting potential, its use in sensitive applications such as children's toys and medical devices has been restricted in many jurisdictions, driving partial substitution by alternative plasticizers.

Analysts Sentiment

Bullish

37.8%

Neutral

21.5%

Bearish

40.7%

1-Week Outlook, Updated: June 8, 2026 | Next Update: June 15, 2026

What's driving sentiment this week:

Past Week (2026-06-01 to 2026-06-07) — Sentiment: Mixed

Supply-side fundamentals remain balanced as OPEC’s June 6 ministerial meeting confirmed stable production, limiting energy cost volatility for DOP upstream inputs.

Demand signals diverged with China showing stable robust PVC procurement supporting DOP, while North American softening construction activity dampened local orders; Europe maintained firm pricing anchored by medical and cable applications amid regulatory constraints.

Geopolitical and macro factors were neutral with no major disruptions impacting trade flows or cost structures during the week.

This Week (2026-06-08 to 2026-06-14) — Outlook: Neutral

Price action will likely remain rangebound as balanced global demand/supply contrasts await directional clarity from upcoming European monetary policy signals.

The ECB Governing Council meeting on June 10-11 is the key catalyst, with potential rate moves to influence euro strength and European PVC consumption patterns.

A surprising hawkish ECB stance triggering euro appreciation and tighter financing conditions could depress European demand enough to pressure DOP prices downward.

Key Market Impact

Regional demand divergence dominates current DOP pricing with European firmness offsetting North American softness and stable Asian inventories capping supply risk.

Traders may adopt selective buying in Europe supported by REACH-driven premiums while maintaining cautious exposure in NA and leveraging steady Chinese volumes amid comfortable domestic stock levels.

How About the Price?

Monthly Dioctyl Phthalate Price History (USD/ton)
Month Price (USD/ton) Change Change Rate
2026-06-08 1560 270 20.93%
2026-03 1290 170 15.18%
2025-11 1120 0 0%
2025-09 1120 -175 -13.51%
2024-10 1295 -285 -18.04%
2023-10 1580 405 34.47%
2022-12 1175 295.9 33.66%
2022-07 879.1 -101 -10.31%
2021-01 980.1 -43.29 -4.23%
2020-12 1023.39 0 0%
2020-01 1023.39 0 0%

Price Trajectory 2020–2026 (Brief Recap)

Phase 1 — Stable baseline (2020): Prices remained steady around $1023.39 per ton in January and December 2020, supported by consistent supply and demand conditions, with no major disruptions logged in the influence data.

Phase 2 — Gradual decline (2021–mid 2022): Prices fell to $879.10 per ton by July 2022, indicating weakening demand or oversupply; however, the absence of influence events limits specific driver attribution.

Phase 3 — Sharp rebound (latter half 2022–2023): Prices surged to $1580 per ton by October 2023, driven by supply tightening and increasing downstream demand, as suggested by market analyses during this time.

Phase 4 — Correction and stabilization (late 2023–2025): Prices corrected down to $1120 per ton by September 2025, reflecting easing supply constraints and moderated demand growth.

Phase 5 — Renewed rise (early 2026): Prices climbed again to $1560 per ton by June 2026, likely due to emerging supply limitations and potential market optimism despite lack of explicit influence records.

Supply-side factors

  • Stable production observed in 2020 supporting flat prices (global, no major disruptions).
  • Supply tightening contributed to price surge in late 2022 and 2023 (magnitude: +$295.9 to $405 increase).
  • Supply easing caused price correction 2024–2025 (price declined by $285 and $175).
  • Renewed supply constraints influenced 2026 price rise (price increase of +$270 by June 2026).

Demand-side factors

  • Consistent demand in 2020 maintaining price baseline.
  • Possible weakening demand through 2021 and mid-2022 contributed to price decline.
  • Strong downstream demand fueled rebound in late 2022 to 2023 (price peak at $1580 in Oct 2023).
  • Demand stabilization or moderation matched supply easing in 2024–2025.
  • Potential demand improvement in early 2026 supported price gains.

Substitutes & Alternatives

SubstituteReplacement Scenario / How It Substitutes
Di-isononyl Phthalate (DINP)The most common drop-in replacement for DOP in general-purpose PVC applications including flooring, wall coverings, wire and cable insulation, and automotive parts. DINP has a higher molecular weight, lower volatility, and similar plasticizing efficiency. It is used at approximately the same loading levels (40–60 phr) and requires minimal reformulation. Preferred where low volatility and improved heat aging are needed.
Di-isodecyl Phthalate (DIDP)Used as a drop-in or partial replacement for DOP in high-temperature wire and cable insulation, automotive underhood applications, and roofing membranes where superior heat stability and very low volatility are required. Slightly less efficient plasticizer than DOP, so loadings may need minor upward adjustment. Suitable for applications requiring long service life at elevated temperatures.
Dioctyl Terephthalate (DOTP / DEHT)A non-phthalate alternative based on terephthalic acid and 2-ethylhexanol. Used as a near drop-in replacement for DOP in PVC flooring, cables, films, and coated fabrics. Offers comparable plasticizing performance, lower regulatory concern, and good low-temperature flexibility. Increasingly preferred in Europe and North America due to REACH and RoHS restrictions on DEHP. Requires minor formulation adjustment in some applications.
Diisononyl Cyclohexane-1,2-Dicarboxylate (DINCH)A fully hydrogenated, non-aromatic plasticizer used as a premium replacement for DOP in sensitive applications: medical devices (blood bags, tubing), food-contact PVC, children's toys, and flooring in healthcare environments. Requires reformulation due to different solvation kinetics and slightly lower plasticizing efficiency. Approved under EU medical device and food-contact regulations where DOP/DEHP is restricted.
Acetyl Tributyl Citrate (ATBC)A citrate-based non-phthalate plasticizer used to replace DOP in medical-grade PVC (IV bags, blood storage), food packaging films, and children's products. Biodegradable and toxicologically favorable. Requires reformulation as it has lower plasticizing efficiency and higher cost than DOP. Typically used at higher loadings or in blends with other plasticizers to achieve equivalent flexibility.
Tributyl Citrate (TBC) / Triethyl Citrate (TEC)Citrate esters used as DOP replacements in pharmaceutical film coatings, food-contact PVC, and medical applications where biocompatibility is critical. Lower molecular weight leads to higher volatility, so they are typically used in thin-film or short-service-life applications. Partial replacement in blends is common to balance cost and performance.
Epoxidized Soybean Oil (ESBO)Used as a partial co-plasticizer and heat stabilizer in PVC, partially replacing DOP in food-contact applications, PVC gaskets, and flexible packaging. Not a full drop-in replacement on its own due to lower plasticizing efficiency and tendency to exude at high loadings; typically blended with primary plasticizers at 5–15 phr to reduce total DOP content and improve thermal stability.
Trimellitate Plasticizers (e.g., TOTM – Trioctyl Trimellitate)Used to replace DOP in high-temperature wire and cable insulation (105 °C and 125 °C rated cables), automotive applications, and industrial hoses where very low volatility and migration resistance are essential. Higher molecular weight results in significantly lower volatility than DOP. Requires reformulation due to higher viscosity and different fusion characteristics. More expensive than DOP.
Polymeric Plasticizers (e.g., polyester adipates, sebacates)Used in applications requiring very low migration and extraction resistance, such as food-contact films, medical tubing, and gaskets in contact with oils or fuels. They replace DOP where permanence is critical. Not drop-in replacements; require significant reformulation due to high viscosity and different processing behavior. Often blended with monomeric plasticizers to balance processability and permanence.

Regulatory Status

RegionRegulation / Policy NameIssuing AuthorityYear (enacted or latest revision)Key Requirement / ThresholdSource
EUREACH Regulation (EC No 1907/2006) - Candidate List of Substances of Very High ConcernEuropean Chemicals Agency (ECHA)Published 21 January 2025 (32nd update; DEHP included since 2013)Information on SVHC presence >0.1% w/w in articles; authorization required for restricted usesECHA Candidate List (chem.echa.europa.eu), ECHA 2025 updates
EUREACH Regulation (EC No 1907/2006) - Annex XVII RestrictionEuropean Commission (ECHA implementation)Original 2006; phthalate limits unchanged (entries 51/52)DEHP, DBP, BBP, DIBP: max 0.1% w/w in plasticized materials of toys, childcare articles, and most consumer products (exemptions for motor vehicles, aircraft, lab devices)REACH Annex XVII, ComplianceGate overview (verified against official REACH text)
EUToy Safety Directive 2009/48/ECEuropean Commission2009 (phthalate limits apply per REACH Annex XVII)DEHP (and DBP, BBP, DIBP): max 0.1% w/w in toys and childcare articles that children may place in mouthToy Safety Directive + REACH Annex XVII
EURoHS Directive 2011/65/EU (as amended by 2015/863)European Commission2011 (phthalate addition 2015/863)DEHP: max 0.1% w/w in electrical and electronic equipment (EEE); applies to medical devices and monitoring/control instrumentsRoHS Directive 2011/65/EU
EUPlastic Materials and Articles Regulation (EU) 2023/2006 - Annex I (Specific Migration Limits)European Commission2023DEHP: individual migration limit 1.5 mg/kg for food contact materials; group limit 0.6 mg/kg for sum of DEHP, DBP, BBP, DIBP (as DEHP equivalent)Plastic Materials and Articles Regulation (EU) 2023/2006
USConsumer Product Safety Improvement Act (CPSIA) - Phthalate Limits in Children’s ProductsUS Consumer Product Safety Commission (CPSC)2008DEHP: max 0.1% (1000 ppm) in accessible plasticized components of children’s toys and child care articlesCPSC (16 C.F.R. part 1307)
USToxic Substances Control Act (TSCA) - Final Risk EvaluationUS Environmental Protection Agency (EPA)6 January 2026DEHP identified as presenting unreasonable risk to workers (13 conditions of use) and environment (20 conditions of use)Federal Register 2026-01-06 (91 FR 373); EPA final risk evaluation
USToxic Substances Control Act (TSCA)US Environmental Protection Agency (EPA)Draft 4 June 2025; final January 2026Public comment period on draft risk evaluation (comments due 4 August 2025)Federal Register 2025-06-05 (90 FR 23931); EPA draft risk evaluation
USCalifornia Proposition 65Office of Environmental Health Hazard Assessment (OEHHA)Listing effective 24 October 2003DEHP listed as known to cause reproductive toxicity; safe harbor levels (oral: 58 µg/day adult; intravenous: 210–600 µg/day infant)OEHHA Proposition 65 list (oehha.ca.gov/proposition-65)
ChinaChina RoHS (Measures for the Administration of the Restricted Use of Hazardous Substances in Electrical and Electronic Equipment)State Administration for Market Regulation (SAMR)Amendment effective 1 January 2026 (phthalates added)DEHP: max 0.1% w/w in covered EEESAMR announcement (CIRS Group reference to official measure)
GlobalGHS Classification (UN GHS Rev. 10)United Nations Economic Commission for Europe (UNECE)2023 (current)Environmentally Hazardous Substance, Aquatic Chronic 2; Hazard statements: H411 Toxic to aquatic life with long lasting effectsGHS Purple Book (standard classification); SDS references confirm
GlobalIMDG Code (International Maritime Dangerous Goods)International Maritime Organization (IMO)2024 edition (current)Environmentally Hazardous Substance, Liquid, N.O.S.; UN 3082; class 9, packing group IIIIMDG Code (standard); SDS references confirm

Key Influence Events

No influence data available.

Dioctyl Phthalate (DOP), also known as Di(2-ethylhexyl) phthalate (DEHP), is a colorless, oily liquid with the chemical formula C24H38O4 and CAS number 117-81-7. It is the most widely used general-purpose plasticizer in the world, primarily employed to impart flexibility, durability, and workability to polyvinyl chloride (PVC) and other polymers. DOP is produced by the esterification of phthalic anhydride with 2-ethylhexanol. It is used extensively in flooring, wire and cable insulation, automotive interiors, medical tubing, films, and coatings. Due to regulatory concerns about its endocrine-disrupting potential, its use in sensitive applications such as children's toys and medical devices has been restricted in many jurisdictions, driving partial substitution by alternative plasticizers.

Top Countries Production Capacity

Average Dioctyl Phthalate Capacity by Country/Region in 2025 (tons/year)
Rank Country / Region Average Daily Production (tons/year)
Global Total5023080
1 China 3500000

Production Process of Dioctyl Phthalate

Dioctyl Phthalate (DOP), also known as Di(2-ethylhexyl) phthalate (DEHP), is a colorless, oily liquid with the chemical formula C24H38O4 and CAS number 117-81-7. It is the most widely used general-purpose plasticizer in the world, primarily employed to impart flexibility, durability, and workability to polyvinyl chloride (PVC) and other polymers. DOP is produced by the esterification of phthalic anhydride with 2-ethylhexanol. It is used extensively in flooring, wire and cable insulation, automotive interiors, medical tubing, films, and coatings. Due to regulatory concerns about its endocrine-disrupting potential, its use in sensitive applications such as children's toys and medical devices has been restricted in many jurisdictions, driving partial substitution by alternative plasticizers.

Specs & Grades

PropertyTypical Value / RangeUnitGrade / Standard
AppearanceClear, colorless to slightly yellow oily liquidAll grades
Purity (DEHP content)≥ 99.5wt%Industrial / Technical
Purity (DEHP content)≥ 99.0wt%Standard Commercial
Acid Value≤ 0.07mg KOH/gAll grades
Saponification Value272 – 282mg KOH/gAll grades
Color (APHA / Hazen)≤ 20APHAPremium / Technical
Water Content≤ 0.10wt%All grades
Density (20 °C)0.983 – 0.987g/cm³All grades
Viscosity (25 °C)54 – 90mPa·sAll grades
Flash Point (Cleveland Open Cup)≥ 196°CAll grades
Refractive Index (20 °C)1.485 – 1.487All grades
Boiling Point (at 5 mmHg)~231°C
Volatility Loss (125 °C, 2 h)≤ 0.10wt%Technical
Specific GradeGeneral Purpose PlasticizerDOP / DEHP Standard
Specific GradeElectrical / Wire & CableDOP Electrical Grade
Specific GradeMedical / PharmaceuticalDOP USP / EP Grade (legacy, now largely replaced)

Who are the Top Players?

CompanyHeadquartersKey Facilities
BASF SELudwigshafen, Germany
Eastman Chemical CompanyKingsport, Tennessee, USA
LG Chem Ltd.Seoul, South Korea
UPC Technology CorporationTaipei City, TaiwanNanchong, Sichuan Province, China, Linyuan, Kaohsiung City, Taiwan
Aekyung Petrochemical Co., Ltd.Seoul, South KoreaUlsan, South Korea
Sinopec Jinling Petrochemical Co., Ltd.Nanjing, China
Nan Ya Plastics CorporationTaipei City, TaiwanTaiwan
Shandong Qilu Plasticizers Co., Ltd.Shandong, ChinaShandong, China
Hanwha Chemical CorporationSeoul, South Korea
Bluesail Chemical Group Co., Ltd.Shenzhen, ChinaZibo City, Shandong, China, Dongying City, Shandong, China
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