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Methyl tert-butyl ether

What is Methyl tert-butyl ether

Methyl tert-butyl ether (MTBE), with the chemical formula (CH3)3COCH3 and CAS number 1634-04-4, is a colorless, volatile, flammable liquid with a distinctive ether-like odor. It is produced by the catalytic reaction of methanol and isobutylene and is used primarily as a high-octane blending component in reformulated gasoline, where it raises the octane number (RON ~118, MON ~100) and provides oxygen content to promote more complete combustion and reduce tailpipe emissions of carbon monoxide and unburned hydrocarbons. MTBE largely replaced tetraethyl lead as an antiknock additive from the 1980s onward. Its use in fuel has declined significantly in the United States since the early 2000s due to groundwater contamination concerns stemming from its high water solubility and poor biodegradability, but it remains widely used in Europe, Asia, and the Middle East. Beyond fuel blending, MTBE serves as a solvent and as a chemical intermediate in the production of isobutylene and high-purity isobutylene via cracking.

Analysts Sentiment

Bullish

54.8%

Neutral

22.6%

Bearish

22.6%

1-Week Outlook, Updated: June 8, 2026 | Next Update: June 15, 2026

What's driving sentiment this week:

Past Week (2026-06-01 to 2026-06-07) — Sentiment: Bullish

China MTBE spot fixed at USD 6,145/ton on 2026-06-04, a firm print that tightens Asian offers and pulls regional benchmarks higher into mid-June.

Demand-side signal is constructive as the 2026-06-05 ICIS read flags volumes pulled forward to beat tariffs, accelerating gasoline-blendstock pull through Asia-US lanes.

Macro tape is mixed-to-supportive: surging Asia-US container rates from 2026-06-05 inflate landed costs and effectively raise the floor on delivered MTBE into US blending pools.

This Week (2026-06-08 to 2026-06-14) — Outlook: Bullish

Expect Asian FOB MTBE to grind higher from the USD 6,145/ton 2026-06-04 anchor, with US Gulf and ARA differentials widening as freight loads onto cargo economics.

The dominant catalyst is the tariff-driven front-loading flagged on 2026-06-05 (expected to keep container rates elevated through the 2026-06-08 to 2026-06-14 window).

A sharp reversal in Asia-US container rates or a China spot break below USD 6,000/ton would neutralize the call and reopen downside on arbitrage cargoes.

Key Market Impact

Tight Asian spot pricing combined with freight inflation is the dominant force, lifting blender replacement cost and squeezing import-parity margins for US and European buyers.

Traders should lengthen Asian MTBE length and lock freight early, while refiners and blenders accelerate June liftings before delivered costs reset higher.

How About the Price?

Monthly Methyl tert-butyl ether Price History (USD/ton)
Month Price (USD/ton) Change Change Rate
2026-01-08 628.4 28.4 4.73%
2025-12 600 0 0%
2025-11 600 0 0%
2025-10 600 0 0%
2025-09 600 0 0%
2025-08 600 0 0%
2025-07 600 0 0%
2025-06 600 0 0%
2025-05 600 0 0%
2025-04 600 0 0%
2025-03 600 0 0%
2025-02 600 0 0%
2025-01 600 0 0%
2024-12 600 0 0%
2024-11 600 0 0%
2024-10 600 0 0%
2024-09 600 0 0%
2024-08 600 0 0%
2024-07 600 0 0%
2024-06 600 0 0%
2024-05 600 0 0%
2024-04 600 0 0%
2024-03 600 0 0%
2024-02 600 0 0%
2024-01 600 0 0%
2023-12 600 0 0%
2023-11 600 0 0%
2023-10 600 0 0%
2023-09 600 0 0%
2023-08 600 0 0%
2023-07 600 0 0%
2023-06 600 0 0%
2023-05 600 0 0%
2023-04 600 0 0%
2023-03 600 0 0%
2023-02 600 0 0%
2023-01 600 0 0%
2022-12 600 0 0%
2022-11 600 0 0%
2022-10 600 0 0%
2022-09 600 0 0%
2022-08 600 0 0%
2022-07 600 0 0%
2022-06 600 0 0%
2022-05 600 0 0%
2022-04 600 0 0%
2022-03 600 0 0%
2022-02 600 0 0%
2022-01 600 0 0%
2021-12 600 0 0%
2021-11 600 0 0%
2021-10 600 0 0%
2021-09 600 0 0%
2021-08 600 0 0%
2021-07 600 0 0%
2021-06 600 0 0%
2021-05 600 0 0%
2021-04 600 0 0%
2021-03 600 0 0%
2021-02 600 0 0%
2021-01 600 0 0%
2020-12 600 0 0%
2020-11 600 0 0%
2020-10 600 0 0%
2020-09 600 0 0%
2020-08 600 0 0%
2020-07 600 0 0%
2020-06 600 0 0%
2020-05 600 0 0%
2020-04 600 0 0%
2020-03 600 0 0%
2020-02 600 0 0%
2020-01 600 0 0%

Price Trajectory 2020–2025 (Brief Recap)

Phase 1 — Stable Pricing (2020–2025): Throughout this period, there were no recorded market influences or events impacting Methyl tert-butyl ether prices, resulting in a consistent price of $600.00 per ton for every month from January 2020 through December 2025.

Phase 2 — Slight Increase (January 2026): In early 2026, the price increased to $628.40 per ton as of January 8, 2026, without any documented market influence or event in the logs to explain this change.

Supply-side factors

    Demand-side factors

      Substitutes & Alternatives

      SubstituteReplacement Scenario / How It Substitutes
      Ethanol (fuel-grade)The most widely adopted drop-in replacement for MTBE as a gasoline oxygenate and octane booster. Following MTBE phase-outs in the US (post-2005), ethanol (typically E10 blends at 10 vol%) replaced MTBE to meet reformulated gasoline oxygen content requirements. Ethanol has a similar RON (~109) and provides comparable octane enhancement. The substitution is largely drop-in at the blending terminal level, though ethanol's higher water affinity requires dedicated, segregated pipeline and storage infrastructure. Partial replacement in specific blends is straightforward; full replacement requires logistics adjustments.
      Ethyl tert-butyl ether (ETBE)A direct structural analog of MTBE produced from isobutylene and ethanol instead of methanol. ETBE is used as a gasoline oxygenate and octane booster (RON ~118, MON ~102) in Europe and Japan, where it is preferred over ethanol because it has lower vapor pressure and lower water solubility. It is a near-drop-in replacement for MTBE in fuel blending with no infrastructure changes required. ETBE can be produced in existing MTBE plants with minimal modification by substituting ethanol for methanol.
      Tert-amyl methyl ether (TAME)Produced from methanol and isoamylene (2-methyl-2-butene or 2-methyl-1-butene) from C5 FCC streams. TAME is used as a partial replacement for MTBE in gasoline blending, offering a lower vapor pressure (beneficial for summer-grade fuels) and similar oxygenate functionality. It is typically used alongside MTBE or ETBE rather than as a complete replacement, and is a drop-in blending component requiring no reformulation of the fuel blend beyond adjusting blend ratios.
      Di-isobutylene (DIB) / AlkylateAlkylate (isooctane-rich product of isobutane alkylation with butylenes) is used as a high-octane, low-vapor-pressure, zero-oxygen gasoline blending component that can replace MTBE's octane contribution in premium and reformulated gasolines. It does not provide oxygen content, so it cannot substitute MTBE where regulatory oxygen mandates apply. In markets where oxygenate mandates have been lifted (e.g., US post-2006 waiver), alkylate is the primary octane-boosting substitute. No reformulation is needed; it is a direct blending component.
      Isooctane (2,2,4-trimethylpentane)High-purity isooctane (RON = 100 by definition) can replace MTBE as an octane enhancer in premium and aviation gasoline blends and in laboratory reference fuel applications. It is more expensive than MTBE and does not provide oxygenate functionality, limiting its use to applications where octane enhancement alone is required and cost is secondary (e.g., racing fuels, avgas blending, calibration standards).
      tert-Butanol (TBA)Can serve as a gasoline oxygenate and octane booster (RON ~105) and was used historically as a co-solvent with methanol in gasoline. TBA is also an intermediate in some MTBE production routes. As a direct MTBE substitute in fuel blending, TBA has a high melting point (25.6°C) that limits its practical use in cold climates without blending adjustments. It is a partial substitute in specific warm-climate or industrial solvent applications.
      Methanol (direct blending)Methanol itself can be blended directly into gasoline (M3, M5, M15 blends) as an oxygenate and octane booster (RON ~133), partially substituting for MTBE's role. However, methanol's very high water affinity, phase-separation risk, and corrosivity toward certain elastomers and metals mean it requires fuel system compatibility measures and is generally not a drop-in replacement. It is used as a direct blend component primarily in China (M15 and M85 programs) and in specific industrial fleet applications.

      Regulatory Status

      RegionRegulation / Policy NameIssuing AuthorityYear (enacted or latest revision)Key Requirement / ThresholdSource
      United StatesClean Air Act Amendments (oxygenate requirements)EPA1990At least 2.0 percent oxygen by weight in reformulated gasoline; refiners could use MTBE or ethanolUS EPA archive on MTBE in fuels
      United StatesEnergy Policy ActCongress / EPA2005Removed oxygenate requirement for reformulated gasoline; no mandate for MTBE in fuelsUS EPA archive on MTBE in fuels
      United StatesTSCA Section 6 rulemaking (MTBE as fuel additive)EPA2000Advance notice of intent to initiate rulemaking to eliminate or limit use as fuel additive; no final regulation adoptedFederal Register / US EPA
      United StatesSecondary Drinking Water AdvisoryEPA1997 (still referenced)20-40 ppb in drinking water for taste and odor; advisory only, no enforceable standardUS EPA archive on MTBE in gasoline
      European UnionREACH Regulation (EC) No 1907/2006ECHA2007 (registration active)Duly registered in 2010 with Chemical Safety Report; no authorisation required; not SVHCECHA dossier and EU Risk Assessment Report
      European UnionREACH (EC) No 1907/2006ECHA2007Low acute toxicity (oral LD50 ~4000 mg/kg); not PBT or vPvBECHA CHEM dossier
      International / GlobalGHS classification (UN model)UNECE / GHSLatest (Rev. 7+)Flammable Liquid Category 2 (H225); Skin Irritation Category 2 (H315); UN Number 2398, Class 3, Packing Group IICarl Roth SDS / Sigma-Aldrich SDS
      International / GlobalIMDG Code (UN Recommendations on Transport of Dangerous Goods)IMOOngoing (current edition)UN 2398, Methyl tert-butyl ether, Class 3, Packing Group II, marine pollutant: noCarl Roth SDS / Sigma-Aldrich SDS
      ChinaMEE fuel quality and environmental compliance standardsMinistry of Ecology and EnvironmentActive (ongoing domestic upgrades)No national ban or phase-out for MTBE as oxygenate; permitted in gasoline blending (domestic production ~16 million tonnes in 2023)Global MTBE market reports citing MEE context

      Key Influence Events

      No influence events available.

      Methyl tert-butyl ether (MTBE), with the chemical formula (CH3)3COCH3 and CAS number 1634-04-4, is a colorless, volatile, flammable liquid with a distinctive ether-like odor. It is produced by the catalytic reaction of methanol and isobutylene and is used primarily as a high-octane blending component in reformulated gasoline, where it raises the octane number (RON ~118, MON ~100) and provides oxygen content to promote more complete combustion and reduce tailpipe emissions of carbon monoxide and unburned hydrocarbons. MTBE largely replaced tetraethyl lead as an antiknock additive from the 1980s onward. Its use in fuel has declined significantly in the United States since the early 2000s due to groundwater contamination concerns stemming from its high water solubility and poor biodegradability, but it remains widely used in Europe, Asia, and the Middle East. Beyond fuel blending, MTBE serves as a solvent and as a chemical intermediate in the production of isobutylene and high-purity isobutylene via cracking.

      Top Countries Production Capacity

      Average Methyl tert-butyl ether Capacity by Country/Region in 2025 (tons/year)
      Rank Country / Region Average Daily Production (tons/year)
      Global Total26200000
      1 China 15000000
      2 United States 2000000
      3 Saudi Arabia 2000000
      4 Europe 1500000
      5 Middle East (excluding Saudi Arabia, Qatar, UAE) 1000000
      6 Other Asia-Pacific 800000
      7 Qatar 650000
      8 Latin America 500000
      9 Other 500000
      10 Russia & Eurasia 400000
      11 Africa 300000
      12 United Arab Emirates 200000
      13 India 200000
      14 Japan 200000
      15 South Korea 150000
      16 Taiwan 100000

      Production Process of Methyl tert-butyl ether

      Methyl tert-butyl ether (MTBE), with the chemical formula (CH3)3COCH3 and CAS number 1634-04-4, is a colorless, volatile, flammable liquid with a distinctive ether-like odor. It is produced by the catalytic reaction of methanol and isobutylene and is used primarily as a high-octane blending component in reformulated gasoline, where it raises the octane number (RON ~118, MON ~100) and provides oxygen content to promote more complete combustion and reduce tailpipe emissions of carbon monoxide and unburned hydrocarbons. MTBE largely replaced tetraethyl lead as an antiknock additive from the 1980s onward. Its use in fuel has declined significantly in the United States since the early 2000s due to groundwater contamination concerns stemming from its high water solubility and poor biodegradability, but it remains widely used in Europe, Asia, and the Middle East. Beyond fuel blending, MTBE serves as a solvent and as a chemical intermediate in the production of isobutylene and high-purity isobutylene via cracking.

      Specs & Grades

      PropertyTypical Value / RangeUnitGrade / Standard
      Purity (MTBE content)≥ 99.0wt%Fuel-grade / Chemical-grade
      Purity (MTBE content)≥ 99.8wt%High-purity / Reagent-grade
      Methanol content≤ 0.5wt%Fuel-grade
      Methanol content≤ 0.05wt%Chemical-grade
      Water content≤ 200ppm (mg/kg)Fuel-grade
      Water content≤ 50ppm (mg/kg)Chemical-grade
      Isobutylene content≤ 200ppmFuel-grade
      Acidity (as acetic acid)≤ 0.001wt%Fuel-grade
      Sulfur content≤ 10mg/kgFuel-grade (EU)
      Density at 15°C740 – 744kg/m³All grades
      Research Octane Number (RON)~118Fuel-grade
      Motor Octane Number (MON)~100Fuel-grade
      Boiling point55.2°CAll grades
      Reid Vapor Pressure (RVP)~55kPaFuel-grade
      Oxygen content~18.2wt%All grades
      Color (APHA)≤ 5APHA unitsChemical-grade

      Who are the Top Players?

      CompanyHeadquartersKey Facilities
      SABICRiyadh, Saudi ArabiaJubail Industrial City, Saudi Arabia
      LyondellBasell IndustriesHouston, Texas, USAChannelview, Texas, USA, Pasadena, Texas, USA, Botlek, Rotterdam, Netherlands
      Evonik IndustriesEssen, GermanyMarl, Germany, Antwerp, Belgium
      SinopecBeijing, ChinaNanjing, China
      Enterprise Products PartnersHouston, Texas, USAMont Belvieu, Texas, USA
      SIBURMoscow, RussiaTogliatti, Russia, Tobolsk, Russia
      PETRONAS Chemicals GroupKuala Lumpur, MalaysiaGebeng, Pahang, Malaysia
      EniMilan, ItalyRavenna, Italy
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